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Have you tried using the two column widget? Here's an example of a two column widget with another two column widget nested inside each side of the initial two column widget http://e-learnabout.com/test-page.php.
For images such as these to line up properly they just need to be centered individually within each side of the two column widget which you can do from the properties tab.
I'm not sure if this will help, let me know if I wasn't understanding your question properly.
I am not really sure what you mean, but I think it might be trying to get say a button to line up with the text describing the link that clicking the button will take you to ? If this is the case then instead of adding the button as an image you can put it into a text widget by typing the text and then using the "insert image" option on the text formatting bar at the top. You can still add a link to the image even if in a text widget.
I hope I haven't totally misunderstood your problem ????